Understanding trends in the mercury oxidation activity of single-atom catalysts

Author:

Yang Weijie123ORCID,Chen Xuelu123ORCID,Feng Yajun123,Wang Fei4ORCID,Gao Zhengyang123,Liu Yanfeng123,Ding Xunlei56ORCID,Li Hao7ORCID

Affiliation:

1. Department of Power Engineering, School of Energy, Power and Mechanical Engineering, North China Electric Power University, Baoding 071003, China

2. Hebei Key Laboratory of Low Carbon and High Efficiency Power Generation Technology, North China Electric Power University, Baoding, 071003, Hebei, China

3. Baoding Key Laboratory of Low Carbon and High Efficiency Power Generation Technology, North China Electric Power University, Baoding, 071003, Hebei, China

4. Key Laboratory of Special Functional Materials for Ecological Environment and Information (Hebei University of Technology), Ministry of Education, Tianjin 300130, China

5. School of Mathematics and Physics, North China Electric Power University, Beijing 102206, China

6. Institute of Clusters and Low Dimensional Nanomaterials, School of Mathematics and Physics, North China Electric Power University, Beijing, China

7. Advanced Institute for Materials Research (WPI-AIMR), Tohoku University, Sendai 980-8577, Japan

Abstract

Transition metal single-atom catalysts with nitrogen-doped carbon substrates were designed and analyzed as the catalysts to oxidize Hg0 with O2, using density functional theory calculations, scaling relation analysis, and microkinetic modeling.

Funder

Natural Science Foundation of Hebei Province

National Natural Science Foundation of China

National Key Research and Development Program of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Environmental Science,Materials Science (miscellaneous)

Reference65 articles.

1. Mercury as a Global Pollutant: Sources, Pathways, and Effects

2. A Holistic Perspective Is Needed To Ensure Success of Minamata Convention on Mercury

3. J.Crawford , EPA Mercury and Air Toxics Standards for new plants nearing finalization, Snl Energy Coal Report, 2013 , pp. 2–3

4. Mercury emissions of a coal-fired power plant in Germany

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