Cage compound Sc5Pt24B12: a Pt-stuffed variant of filled skutterudite structure. Electronic and structural properties

Author:

Salamakha Leonid12ORCID,Sologub Oksana1ORCID,Stöger Berthold3ORCID,Michor Herwig1ORCID,Bauer Ernst1ORCID,Rogl Peter F.4ORCID

Affiliation:

1. Institute of Solid State Physics, TU Wien, A-1040 Vienna, Austria

2. Department of Physics of Metals, L′viv National University, L′viv, Ukraine

3. X-Ray Center, TU Wien, A-1060 Vienna, Austria

4. Institute of Materials Chemistry, University of Vienna, A-1090 Vienna, Austria

Abstract

The cage compound Sc5Pt24B12 (a) is characterized by an anionic covalently bonded framework of [BPt6] trigonal prisms (b) embedding scandium cations in icosahedral (c) and cubooctahedral (d) cavities.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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