Triazenide-supported [Cu4S] structural mimics of CuZ that mediate N2O disproportionation rather than reduction-Reference-Cited by-同舟云学术

Triazenide-supported [Cu₄S] structural mimics of Cu_Z that mediate N₂O disproportionation rather than reduction

Published:2024 Issue:5 Volume:15 Page:1820-1828
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Mankad Neal P.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Illinois Chicago, Chicago, IL 60607, USA

Abstract

Factors controlling N2O reduction vs. disproportionation selectivity are examined by comparing reactivity of different synthetic tetracopper sulfide clusters that mimic the structure of the CuZ active site of nitrous oxide reductase.

Funder

National Institute of General Medical Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC05451A

Reference35 articles.

1. Greenhouse gas growth rates

2. Nitrous Oxide (N 2 O): The Dominant Ozone-Depleting Substance Emitted in the 21st Century

3. A comprehensive quantification of global nitrous oxide sources and sinks

4. Source and reduction of nitrous oxide

5. Physical properties and mechanisms of formation of nitrous oxide

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