Successive short- and long-range magnetic ordering in rosiaite-type CoGeTeO6 prepared by ion-exchange reaction

Author:

Bazhan Roman V.1,Nalbandyan Vladimir B.1ORCID,Vasilchikova Tatyana M.23ORCID,Koo Hyun-Joo4,Whangbo Myung-Hwan45,Vasiliev Alexander N.3ORCID

Affiliation:

1. Department of Chemistry, Southern Federal University, Rostov-on-Don 344090, Russia

2. Department of Low Temperature Physics and Superconductivity, M.V. Lomonosov Moscow State University, Moscow 119991, Russia

3. Functional Quantum Materials Laboratory, National University of Science and Technology “MISiS”, Moscow 119049, Russia

4. Department of Chemistry and Research Institute for Basic Sciences, Kyung Hee University, Seoul 02447, Republic of Korea

5. Department of Chemistry, North Carolina State University, Raleigh, NC 27695-8204, USA

Abstract

CoGeTeO6, the missing member of the rosiaite family, was obtained from Na2GeTeO6 by ion-exchange reaction. It undergoes short- and long-range magnetic ordering well separated with respect to temperature due to the spin frustration.

Funder

Russian Foundation for Basic Research

Megagrants

Ministry of Education

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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