Facial <i>vs.</i> meridional coordination in gaseous Ni(<scp>ii</scp>)–hexacyclen complexes revealed with infrared ion spectroscopy-Reference-Cited by-同舟云学术

Facial vs. meridional coordination in gaseous Ni(ii)–hexacyclen complexes revealed with infrared ion spectroscopy

Published:2022 Issue:43 Volume:24 Page:26890-26897
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Munshi Musleh Uddin¹^ORCID,Berden Giel²^ORCID,Oomens Jos²³^ORCID

Affiliation:

1. Department of Chemistry, Sogang University, Seoul 04107, Korea

2. Radboud University, Institute for Molecules and Materials, FELIX Laboratory, Toernooiveld 7, 6525 ED Nijmegen, The Netherlands

3. University of Amsterdam, Science Park 904, 1098XH Amsterdam, The Netherlands

Abstract

The infrared multiple-photon dissociation (IRMPD) spectrum of the hexa-coordinated complex of hexacyclen (18-azacrown-6) with Ni2+ shows that the complex has a meridional – and not facial – chelation geometry in the gas phase.

Funder

Nederlandse Organisatie voor Wetenschappelijk Onderzoek

National Research Foundation of Korea

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP03871D

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