Asymmetric Lewis acid catalysis directed by octahedral rhodium centrochirality-Reference-Cited by-同舟云学术

Asymmetric Lewis acid catalysis directed by octahedral rhodium centrochirality

Published:2015 Issue:2 Volume:6 Page:1094-1100
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Wang Chuanyong¹²³⁴,Chen Liang-An⁵⁶⁷⁸⁹,Huo Haohua¹²³⁴,Shen Xiaodong¹²³⁴,Harms Klaus¹²³⁴,Gong Lei⁵⁶⁷⁸⁹,Meggers Eric¹²³⁴⁵

Affiliation:

1. Fachbereich Chemie

2. Philipps-Universität Marburg

3. 35043 Marburg

4. Germany

5. Department of Chemical Biology and Key Laboratory for Chemical Biology of Fujian Province

6. College of Chemistry and Chemical Engineering

7. Xiamen University

8. Xiamen 361005

9. People's Republic of China

Abstract

A chiral-at-metal octahedral rhodium(iii) complex serves as an effective asymmetric catalyst for Michael additions (electrophile activation) and α-aminations (nucleophile activation).

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C4SC03101F

Reference62 articles.

1. Chiral Lewis Acids in Catalytic Asymmetric Reactions

2. Designer Lewis acid catalysts—bulky aluminium reagents for selective organic synthesis

3. Catalytic Asymmetric Addition Reactions of Carbonyls. A Common Catalytic Approach

4. Chiral Bis(oxazoline) Copper(II) Complexes: Versatile Catalysts for Enantioselective Cycloaddition, Aldol, Michael, and Carbonyl Ene Reactions

5. C2-Symmetric Chiral Bis(Oxazoline) Ligands in Asymmetric Catalysis

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