Guest size effects on a robust structure of semiclathrate hydrates and their thermophysical properties

Author:

Muromachi Sanehiro1ORCID,Takeya Satoshi2

Affiliation:

1. Energy Process Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), 16-1 Onogawa, Tsukuba, 305-8569, Japan

2. National Metrology Institute of Japan (NMIJ), National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi, Tsukuba, 305-8565, Japan

Abstract

Structure and thermal properties of N3444Cl and N4444Cl semiclathrates characterized. A robustness of the hydrate structure identified for customizing their properties for practical applications.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference75 articles.

1. D. W.Davidson , Water: a comprehensive treatise , Plenum press , New York , 1973 , vol. 2, pp. 115–661

2. G. A.Jeffrey , Inclusion Compounds , Academic Press , London , 1984 , vol. 1, pp. 135–190

3. J. A.Ripmeester and S.Alavi , Clathrate Hydrates , John Wiley & Sons, Ltd , 2022

4. Clathrate polyhydrates of peralkylonium salts and their analogs

5. Tetra-n-butylammonium bromide–water (1/38)

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