Regulating the selective adsorption of OH* over the equatorial position of Co3O4via doping of Ru ions for efficient water oxidation reaction

Author:

Madhu Ragunath12ORCID,Karmakar Arun12ORCID,Arunachalam Preethi3,Muthukumar Jaisakthi3,Gudlur Pradeep4,Kundu Subrata12ORCID

Affiliation:

1. Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India

2. Electrochemical Process Engineering (EPE) Division, CSIR-Central Electrochemical Research Institute (CECRI), Karaikudi 630003, Tamil Nadu, India

3. Centre for Education (CFE), CSIR-Central Electrochemical Research Institute (CECRI), Karaikudi 630 003, Tamil Nadu, India

4. Department of Mechanical Engineering, Union College, 807 Union Street, Schenectady, NY, 12308, USA

Abstract

The synthesized Ru-Co3O4 delivers a high performance towards the OER in alkaline (292 mV) and acidic (365 mV) media. Structural optimization demonstrates the distortion of bond length favours the selective adsorption of OH which facilitates the OER.

Funder

Department of Science and Technology, Ministry of Science and Technology, India

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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