Quadrol-Pd(ii) complexes: phosphine-free precatalysts for the room-temperature Suzuki–Miyaura synthesis of nucleoside analogues in aqueous media

Author:

Serrano José Luis1ORCID,Gaware Sujeet2,Pérez Jose Antonio1,Pérez José1,Lozano Pedro3ORCID,Kori Santosh24,Dandela Rambabu2ORCID,Sanghvi Yogesh S.5,Kapdi Anant R.4ORCID

Affiliation:

1. Departamento de Ingeniería Química y Ambiental. Área de Química Inorgánica, Universidad Politécnica de Cartagena member of European University of Technology, 30203 Cartagena, Spain

2. Department of Chemistry, Institute of Chemical Technology-Indian Oil Odisha Campus, IIT Kharagpur Extension Centre, Mouza Samantpuri, Bhubaneswar 751013, Odisha, India

3. Departamento de Bioquímica y Biología Molecular B e Inmunología, Facultad de Química, Regional Campus of International Excellence “Campus Mare Nostrum”, Universidad de Murcia, 30071 Murcia, Spain

4. Department of Chemistry, Institute of Chemical Technology, Mumbai, Nathalal Road, Matunga, Mumbai-400019, India

5. Rasayan Inc. 2802, Crystal Ridge Road, Encinitas, California, 92024-6615, USA

Abstract

Quadrol begins a new as hydrophilic ligand for Pd-catalyzed Suzuki nucleoside modification in water, promoting a room temperature unseen protocol.

Funder

Ministerio de Ciencia e Innovación

Fundación Séneca

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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