Synthesis and structures of mono- and di-nuclear aluminium and zinc complexes bearing α-diimine and related ligands, and their use in the ring opening polymerization of cyclic esters
Author:
Affiliation:
1. College of Chemistry and Material Science
2. Northwest University
3. 710069 Xi'an
4. China
5. Department of Chemistry & Biochemistry
6. The University of Hull
7. Hull
8. UK
Abstract
Multi-metallic complexes (of Al, Zn) derived from imine-based ligands effectively operate as catalysts for the ring opening polymerization (ROP) of ε-caprolactone (ε-CL), δ-valerolactone (δ-VL) and co-polymerization thereof.
Funder
China Postdoctoral Science Foundation
Northwest University
Engineering and Physical Sciences Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/DT/C9DT04332B
Reference82 articles.
1. Polymerization of lactide and related cyclic esters by discrete metal complexes
2. Controlled Ring-Opening Polymerization of Lactide and Glycolide
3. Synthesis of polycaprolactone: a review
4. Stereocontrolled ring-opening polymerization of cyclic esters: synthesis of new polyester microstructures
5. Metal catalysts for ε-caprolactone polymerisation
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