Reversible carbon–boron bond formation at platinum centers through σ-BH complexes-Reference-Cited by-同舟云学术

Reversible carbon–boron bond formation at platinum centers through σ-BH complexes

Published:2021 Issue:5 Volume:12 Page:1647-1655
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Ríos Pablo¹²³⁴⁵^ORCID,Martín-de la Calle Rocío¹²³⁴⁵,Vidossich Pietro⁶⁷⁸⁹,Fernández-de-Córdova Francisco José¹²³⁴⁵,Lledós Agustí¹⁰¹¹¹²¹³,Conejero Salvador¹²³⁴⁵^ORCID

Affiliation:

1. Instituto de Investigaciones Químicas (IIQ)

2. Departamento de Química Inorgánica

3. CSIC and Universidad de Sevilla

4. Centro de Innovación en Química Avanzada (ORFEO-CINQA)

5. Sevilla

6. Molecular Modeling & Drug Discovery Laboratory

7. Istituto Italiano di Tecnologia

8. 16163 Genoa

9. Italy

10. Departament de Química

11. Universitat Autònoma de Barcelona

12. Edifici Cn

13. Spain

Abstract

A reversible carbon–boron bond formation has been observed in the reaction of the coordinatively unsaturated, cyclometalated, Pt(ii) complex [Pt(I^tBuⁱPr′)(I^tBuⁱPr)][BAr^F], 1, with tricoordinated boranes HBR₂.

Funder

Ministerio de Ciencia e Innovación

Ministerio de Economía, Industria y Competitividad, Gobierno de España

Consejo Superior de Investigaciones Científicas

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D0SC05522K

Reference60 articles.

1. Earth-abundant transition metal catalysts for alkene hydrosilylation and hydroboration