Synthesis of N-heterocyclic carbene (NHC)-Au/Ag/Cu benzotriazolyl complexes and their catalytic activity in propargylamide cycloisomerization and carbonyl hydrosilylation reactions-Reference-Cited by-同舟云学术

Synthesis of N-heterocyclic carbene (NHC)-Au/Ag/Cu benzotriazolyl complexes and their catalytic activity in propargylamide cycloisomerization and carbonyl hydrosilylation reactions

Published:2024 Issue:26 Volume:53 Page:11001-11008
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kaplanai Entzy¹^ORCID,Tzouras Nikolaos V.¹²^ORCID,Tsoureas Nikolaos¹,Bracho Pozsoni Nestor²,Bhandary Subhrajyoti²,Van Hecke Kristof¹^ORCID,Nolan Steven P.²^ORCID,Vougioukalakis Georgios C.¹^ORCID

Affiliation:

1. Department of Chemistry, National and Kapodistrian University of Athens, Panepistimiopolis, 15771, Athens, Greece

2. Department of Chemistry and Centre of Sustainable Chemistry, Ghent University, Krijgslaan 281, S-3, 9000 Ghent, Belgium

Abstract

Facile access to a new family of Au-, Ag- and Cu-based Carbene-Metal-Amide (CMA) complexes is reported. These stable complexes bear the benzotriazolyl anion as the amido fragment, and are evaluated as (pre)catalysts in propargylamide cycloisomerizations and carbonyl hydrosilylations.

Funder

Hellenic Foundation for Research and Innovation

Fonds Wetenschappelijk Onderzoek

Bijzonder Onderzoeksfonds

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT01414F

Reference43 articles.

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