Aqueous Suzuki couplings mediated by a hydrophobic catalyst

Author:

Hong Sheng-Bo1,Liang Lan-Chang123ORCID

Affiliation:

1. Department of Chemistry, National Sun Yat-sen University, Kaohsiung 80424, Taiwan

2. Department of Medicinal and Applied Chemistry, Kaohsiung Medical University, Kaohsiung 80708, Taiwan

3. School of Pharmacy, Kaohsiung Medical University, Kaohsiung 80708, Taiwan

Abstract

Though hydrophobic, the amido PNP complex [(Ph2P-o-C6H4)2N]PdCl is a competent catalyst in aqueous Suzuki couplings under aerobic conditions without the necessity of amphiphiles even in the presence of an excess amount of mercury.

Funder

Ministry of Science and Technology, Taiwan

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference58 articles.

1. Ni- and Fe-Based Cross-Coupling Reactions , ed. A. Correa , Springer Cham , Switzerland , 2017

2. New Trends in Cross-Coupling: Theory and Applications , ed. T. Colacot , The Royal Society of Chemistry , Cambridge , 2015

3. Copper-Mediated Cross-Coupling Reactions , eds. G. Evano and N. Blanchard , Wiley , 2013

4. Applied Cross-Coupling Reactions , ed. Y. Nishihara , Springer Berlin , Heidelberg , 2013

5. Palladium-Catalyzed Coupling Reactions: Practical Aspects and Future Developments , ed. Á. Molnár , Wiley-VCH , Weinheim, Germany , 2013

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