Tailoring Lewis/Brønsted acid properties of MOF nodes via hydrothermal and solvothermal synthesis: simple approach with exceptional catalytic implications

Author:

Rojas-Buzo Sergio1234ORCID,Bohigues Benjamin1234,Lopes Christian W.5678ORCID,Meira Débora M.910111213,Boronat Mercedes1234ORCID,Moliner Manuel1234ORCID,Corma Avelino1234ORCID

Affiliation:

1. Instituto de Tecnología Química

2. Universitat Politècnica de València - Consejo Superior de Investigaciones Científicas

3. 46022 Valencia

4. Spain

5. Institute of Chemistry

6. Universidade Federal do Rio Grande do Sul – UFRGS

7. 91501-970 Porto Alegre

8. Brazil

9. CLS@APS, Advanced Photon Source

10. Argonne National Laboratory

11. Argonne

12. USA

13. Canadian Light Source Inc.

Abstract

The Brønsted/Lewis acid properties of Hf-MOF-808 can be tuned by simply controlling the solvent employed in its synthesis, with direct catalytic implications on the activity and selectivity of organic reactions sensitive to the active site nature.

Funder

Ministerio de Ciencia, Innovación y Universidades

Canadian Light Source

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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