Tailored amorphization of graphitic carbon nitride triggers superior photocatalytic C–C coupling towards the synthesis of perfluoroalkyl derivatives

Author:

Longobardo Francesco1ORCID,Gentile Giuseppe1,Criado Alejandro2ORCID,Actis Arianna3,Colussi Sara4ORCID,Dal Santo Vladimiro5,Chiesa Mario3ORCID,Filippini Giacomo1ORCID,Fornasiero Paolo167ORCID,Prato Maurizio1689ORCID,Melchionna Michele16ORCID

Affiliation:

1. Department of Chemical and Pharmaceutical Sciences, University of Trieste, Via L. Giorgieri 1, 34127 Trieste, Italy

2. Universidade da Coruña, Centro de Investigacións Científicas Avanzadas (CICA), Rúa As Carballeiras, 15071, A Coruña, Spain

3. Department of Chemistry and NIS Centre of Excellence, University of Torino, Via Giuria 9, 10125 Torino, Italy

4. Dipartimento Politecnico, University of Udine, Unità di Ricerca INSTM Udine, via del Cotonificio 108, 33100 Udine, Italy

5. Consiglio Nazionale delle Ricerche – Istituto di Scienze Tecnologie Chimiche “Giulio Natta” (CNR-SCITEC), Via C. Golgi 19, I-20133 Milano, Italy

6. Consorzio Interuniversitario Nazionale per la Scienza e Tecnologia dei Materiali (INSTM), Unit of Trieste, via L. Giorgieri 1, 34127 Trieste, Italy

7. Istituto di Chimica dei Composti Organometallici (CNR-ICCOM), Via Madonna del Piano 10, 50019, Sesto Fiorentino, Italy

8. Center for Cooperative Research in Biomaterials (CIC biomaGUNE), Basque Research and Technology Alliance (BRTA), San Sebastián, Spain

9. Ikerbasque, Basque Foundation for Science, Bilbao, Spain

Abstract

Modified carbon nitrides were prepared from graphitic carbon nitride by thermal amorphization. The investigation of the amorphization/catalytic activity relationship was carried out in the context of perfluoroalkyl compound synthesis.

Funder

Università degli Studi di Trieste

Ministero dell’Istruzione, dell’Università e della Ricerca

Agencia Estatal de Investigación

Xunta de Galicia

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Materials Science

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