On the microscopic origin of the cryoprotective effect in lysine solutions

Author:

Henao Andrés12345ORCID,Ruiz Guadalupe N.12345ORCID,Steinke Nicola6789,Cerveny Silvina1011125,Macovez Roberto12345ORCID,Guàrdia Elvira13214155ORCID,Busch Sebastian1617189ORCID,McLain Sylvia E.1920212223ORCID,Lorenz Christian D.24252623ORCID,Pardo Luis Carlos12345ORCID

Affiliation:

1. Grup de Caracterització de Materials

2. Departament de Física

3. ETSEIB, Universitat Politècnica de Catalunya

4. E-08019 Barcelona

5. Spain

6. Center for Marine Environmental Sciences (MARUM)

7. University of Bremen

8. 28359 Bremen

9. Germany

10. Centro de Física de Materiales (CSIC-UPV/EHU)-Material Physics Centre (MPC)

11. Donostia International Physics Center (DIPC)

12. 20018 San Sebastián

13. Grup de Simulació per Ordinador en Matèria Condensada

14. Universitat Politècnica de Catalunya

15. E-08034 Barcelona

16. German Engineering Materials Science Centre (GEMS) at Heinz Maier-Leibnitz Zentrum (MLZ)

17. Helmholtz-Zentrum Geesthacht GmbH

18. 85747 Garching bei München

19. Department of Chemistry

20. School of Life Sciences

21. University of Sussex

22. Brighton

23. UK

24. Department of Physics

25. King's College London

26. London

Abstract

Lysine cryoprotective properties are due to the tight bonding of the first hydration Shell to the amino acid. However this effect is only possible for concentration up to 5.4 water molecules per lysine.

Funder

Ministerio de Economía y Competitividad

Generalitat de Catalunya

Consejo Superior de Investigaciones Científicas

Science and Technology Facilities Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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