Selective oxymetalation of terminal alkynes via 6-endo cyclization: mechanistic investigation and application to the efficient synthesis of 4-substituted isocoumarins-Reference-Cited by-同舟云学术

Selective oxymetalation of terminal alkynes via 6-endo cyclization: mechanistic investigation and application to the efficient synthesis of 4-substituted isocoumarins

Published:2018 Issue:28 Volume:9 Page:6041-6052
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Kita Yuji¹²³⁴⁵^ORCID,Yata Tetsuji¹²³⁴⁵^ORCID,Nishimoto Yoshihiro⁶²³⁴⁵^ORCID,Chiba Kouji⁷⁸⁹⁵,Yasuda Makoto¹²³⁴⁵^ORCID

Affiliation:

1. Department of Applied Chemistry

2. Graduate School of Engineering

3. Osaka University

4. Osaka 565-0871

5. Japan

6. Frontier Research Base for Global Young Researchers Center for Open Innovation Research and Education (COiRE)

7. Material Science Division

8. MOLSIS Inc.

9. Tokyo 104-0033

Abstract

The oxymetalation of terminal alkynes proceeded in a 6-endo cyclization manner with the use of indium or gallium trihalide.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C8SC01537F

Reference106 articles.

1. Docking and scoring in virtual screening for drug discovery: methods and applications

2. The Recent Impact of Solid-Phase Synthesis on Medicinally Relevant Benzoannelated Oxygen Heterocycles

3. The photochemistry of iminium salts and related heteroaromatic systems

4. Organic Photoredox Catalysis

Cited by 39 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Total Synthesis of Ganoapplanin Enabled by a Radical Addition/Aldol Reaction Cascade;Journal of the American Chemical Society;2024-08-07

2. Alkoxycarbonyl Groups in Metalloesters Showing Oxocarbenium‐like Structure and Alkylating Reactivity;Angewandte Chemie International Edition;2024-04-10

3. Alkoxycarbonyl Groups in Metalloesters Showing Oxocarbenium‐like Structure and Alkylating Reactivity;Angewandte Chemie;2024-04-10

4. Stereospecific Indium(III)‐Catalysed Tandem Cycloisomerization of Functionalized 1,6‐enynes: Scope and Mechanistic Insights;Advanced Synthesis & Catalysis;2024-01-10

5. Recent advances in synthesis of isocoumarins: An overview;Tetrahedron;2024-01