A heterometallic (Fe6Na8) cage-like silsesquioxane: synthesis, structure, spin glass behavior and high catalytic activity

Author:

Bilyachenko Alexey N.12345,Levitsky Mikhail M.1234,Yalymov Alexey I.1234,Korlyukov Alexander A.12346,Vologzhanina Anna V.1234,Kozlov Yuriy N.72348,Shul'pina Lidia S.1234,Nesterov Dmytro S.910111213ORCID,Pombeiro Armando J. L.910111213,Lamaty Frédéric1415161718,Bantreil Xavier1415161718,Fetre Amandine1415161718,Liu Diyang1415161718,Martinez Jean1415161718,Long Jérôme19161820,Larionova Joulia19161820,Guari Yannick19161820,Trigub Alexander L.21224,Zubavichus Yan V.21224,Golub Igor E.1234,Filippov Oleg A.1234,Shubina Elena S.1234,Shul'pin Georgiy B.72348

Affiliation:

1. Nesmeyanov Institute of Organoelement Compounds

2. Russian Academy of Sciences

3. 119991 Moscow

4. Russia

5. People's Friendship University of Russia

6. Pirogov Russian National Research Medical University

7. Semenov Institute of Chemical Physics

8. Plekhanov Russian University of Economics

9. Centro de Química Estrutural

10. Instituto Superior Técnico

11. Universidade de Lisboa

12. 1049-001 Lisboa

13. Portugal

14. Institut des Biomolécules Max Mousseron (IBMM)

15. UMR 5247, CNRS

16. Université de Montpellier

17. ENSCM

18. 34095 Montpellier cedex 5

19. ICGM – UMR5253 – Equipe IMNO

20. France

21. National Research Center “Kurchatov Institute”

22. 123098 Moscow

Abstract

The exotic “Asian Lantern” heterometallic cage silsesquioxane [(PhSiO1.5)20(FeO1.5)6(NaO0.5)8(n-BuOH)9.6(C7H8)] (I) was obtained and characterized by X-ray diffraction, EXAFS, topological analyses and DFT calculation.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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