Proton transfer mediated recognition of amines by ionizable macrocyclic receptors

Author:

Gattuso Giuseppe1ORCID,Crisafulli Daniele1ORCID,Milone Marco1ORCID,Mancuso Francesca1ORCID,Pisagatti Ilenia1ORCID,Notti Anna1ORCID,Parisi Melchiorre F.1ORCID

Affiliation:

1. Dipartimento di Scienze Chimiche, Biologiche, Farmaceutiche ed Ambientali, Università degli Studi di Messina, Viale F. Stagno d’Alcontres, 31, 98166 Messina, Italy

Abstract

Host-to-guest proton transfer triggers the recognition between ionizable macrocyclic receptors and amines, providing overall-neutral, internally ion-paired alkylammonium complexes with ionized macrocycles as counterions.

Funder

Ministero dell’Istruzione, dell’Università e della Ricerca

Università degli Studi di Messina

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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