Sustainable and highly controlled aryl couplings revealed by systematic assessment of photoactivatable linkers-Reference-Cited by-同舟云学术

Sustainable and highly controlled aryl couplings revealed by systematic assessment of photoactivatable linkers

Published:2022 Issue:19 Volume:13 Page:5680-5686
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Haensch Veit G.¹^ORCID,Neuwirth Toni¹^ORCID,Bergner Alexander¹,Bruhnke Jakob¹^ORCID,Kloss Florian²,Hertweck Christian¹³^ORCID

Affiliation:

1. Department of Biomolecular Chemistry, Leibniz Institute for Natural Product Research and Infection Biology (HKI), Beutenbergstr. 11a, 07745 Jena, Germany

2. Transfer Group Anti-infectives, Leibniz Institute for Natural Product Research and Infection Biology (HKI), 07745 Jena, Germany

3. Faculty of Biological Sciences, Friedrich Schiller University Jena, 07743 Jena, Germany

Abstract

A series of photoactivatable linkers for metal-free biphenyl synthesis is presented. Alternative substrates for the photosplicing reaction can reduce toxic byproducts and problematic starting materials.

Funder

Deutsche Forschungsgemeinschaft

Bundesministerium für Bildung und Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC00886F

Reference31 articles.

1. Synthesis of biaryls using aryne intermediates

2. Transition-Metal-Free Atropo-Selective Synthesis of Biaryl Compounds Based on Arynes

3. Uncatalyzed and Solvent-Free Multicomponent Process for the Synthesis of Biphenyl-2-carbonitrile Derivatives

4. Transition metal-catalyzed decarboxylative cross-coupling reactions

5. Transition-metal catalyzed oxidative cross-coupling reactions to form C–C bonds involving organometallic reagents as nucleophiles

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