Highly selective Suzuki reaction catalysed by a molecular Pd–P-MOF catalyst under mild conditions: role of ligands and palladium speciation

Author:

Cartagenova Daniele1ORCID,Bachmann Stephan2,Püntener Kurt2,Scalone Michelangelo2,Newton Mark A.3ORCID,Peixoto Esteves Fabio A.1ORCID,Rohrbach Thomas1,Zimmermann Patrik P.1,van Bokhoven Jeroen A.13ORCID,Ranocchiari Marco1ORCID

Affiliation:

1. Laboratory for Catalysis and Sustainable Chemistry, Paul Scherrer Institut, Forschungsstrasse 111, 5232 Villigen PSI, Switzerland

2. Pharmaceutical Division, Synthetic Molecules Technical Development, Department of Process Chemistry and Catalysis, F. Hoffmann-La Roche Ltd, Grenzacherstrasse 124, 4070 Basel, Switzerland

3. Department of Chemistry and Applied Biosciences, ETH Zürich, Vladimir-Prelog-Weg 1-5, 8093 Zurich, Switzerland

Abstract

A phosphine-functionalized MOF was used to prepare molecularly-defined palladium catalysts, active for Suzuki coupling in mild conditions. Their selectivity was correlated with the nature of the catalytic active site via XAS and NMR.

Funder

F. Hoffmann-La Roche

Energy System Integration, Paul Scherrer Institut

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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