Glassy dynamics in polyalcohols: intermolecular simplicity <i>vs.</i> intramolecular complexity-Reference-Cited by-同舟云学术

Glassy dynamics in polyalcohols: intermolecular simplicity vs. intramolecular complexity

Published:2022 Issue:30 Volume:24 Page:18272-18280
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Böhmer Till¹^ORCID,Gabriel Jan Philipp²^ORCID,Zeißler Rolf¹^ORCID,Richter Timo¹,Blochowicz Thomas¹^ORCID

Affiliation:

1. Institute for Condensed Matter Physics, Technical University Darmstadt, Darmstadt, Germany

2. Glass and Time, IMFUFA, Department of Science and Environment, Roskilde University, Roskilde, Denmark

Abstract

We show that intramolecular dynamics can induce significant broadening of the spectral shape of the α-process in polyalcohols (PAs). The effect is only observed in long-chained PAs, like sorbitol, and is absent in short-chained PAs, like glycerol.

Funder

Deutsche Forschungsgemeinschaft

Villum Fonden

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP01969H

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