Rapid one-pot synthesis of tapered star copolymers via ultra-fast coupling of polystyryllithium chain ends-Reference-Cited by-同舟云学术

Rapid one-pot synthesis of tapered star copolymers via ultra-fast coupling of polystyryllithium chain ends

Published:2019 Issue:14 Volume:10 Page:1762-1768
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

von Tiedemann Philipp¹²³⁴⁵,Maciol Kamil¹²³⁴,Preis Jasmin⁶⁷⁴,Sajkiewicz Paweł⁸⁹¹⁰¹¹,Frey Holger¹²³⁴^ORCID

Affiliation:

1. Institute of Organic Chemistry

2. Johannes Gutenberg University

3. 55128 Mainz

4. Germany

5. Graduate School Materials Science in Mainz

6. PSS Polymer Standards Service GmbH

7. 55120 Mainz

8. Institute of Fundamental Technological Research

9. Polish Academy of Sciences

10. 02-106 Warsaw

11. Poland

Abstract

Efficient coupling of sterically demanding polystyryllithium (PS-Li) chain ends is achieved using tetra[3-(chloro-dimethylsilyl)propyl]silane (TCDMSPS) as a linking agent. This general approach is employed for the rapid synthesis of tapered star copolymers.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2019/PY/C8PY01656A

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