A naphthalene-based heterobimetallic triazolylidene Ir<sup>III</sup>/Pd<sup>II</sup> complex: regioselective to regiospecific C–H activation, tandem catalysis and a copper-free Sonogashira reaction-Reference-Cited by-同舟云学术

A naphthalene-based heterobimetallic triazolylidene Ir^III/Pd^II complex: regioselective to regiospecific C–H activation, tandem catalysis and a copper-free Sonogashira reaction

Published:2023 Issue:8 Volume:52 Page:2272-2281
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Majumder Adhir¹,Naskar Rajat¹,Roy Pallabi¹,Mondal Bhaskar¹,Garai Somenath²,Maity Ramananda¹^ORCID

Affiliation:

1. Department of Chemistry, University of Calcutta, Kolkata, West Bengal, 700009, India

2. Department of Chemistry, Institute of Science, Banaras Hindu University, Varanasi 221 005, Uttar Pradesh, India

Abstract

A rare version of naphthalene-based heterobimetallic PdII/IrIII complex possessing cyclometalated mesoionic bis-carbene (MIC) ligand is presented. The complex has been employed as pre-catalyst in the tandem Suzuki−Miyaura/transfer hydrogenation reaction.

Funder

Science and Engineering Research Board

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D2DT03508A

Reference73 articles.

1. Smart N-Heterocyclic Carbene Ligands in Catalysis

2. An overview of N-heterocyclic carbenes