New members of the polynuclear manganese family: MnII2MnIII2 single-molecule magnets and MnII3MnIII8 antiferromagnetic complexes. Synthesis and magnetostructural correlations-Reference-Cited by-同舟云学术

New members of the polynuclear manganese family: MnII2MnIII2 single-molecule magnets and MnII3MnIII8 antiferromagnetic complexes. Synthesis and magnetostructural correlations

Published:2020 Issue:40 Volume:49 Page:13970-13985
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Reis Conceição Nuno¹²³⁴⁵^ORCID,Nesterova Oksana V.¹²³⁴⁵^ORCID,Rajnák Cyril⁶⁷⁸⁹¹⁰^ORCID,Boča Roman⁶⁷⁸⁹¹⁰^ORCID,Pombeiro Armando J. L.¹²³⁴⁵^ORCID,Guedes da Silva M. Fátima C.¹²³⁴⁵^ORCID,Nesterov Dmytro S.¹²³⁴⁵^ORCID

Affiliation:

1. Centro de Química Estrutural

2. Instituto Superior Técnico

3. Universidade de Lisboa

4. 1049-001 Lisboa

5. Portugal

6. Department of Chemistry

7. Faculty of Natural Sciences

8. University of SS Cyril and Methodius

9. 917 01 Trnava

10. Slovakia

Abstract

Three novel Mn₄ and Mn₁₁ complexes were synthesized and characterized. Tetranuclear complexes behave as single-molecule magnets with a high energy barrier.

Funder

Fundação para a Ciência e a Tecnologia

Vedecká Grantová Agentúra MŠVVaŠ SR a SAV

Agentúra na Podporu Výskumu a Vývoja

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT02652B

Reference75 articles.

1. Magnetic bistability in a metal-ion cluster