Coupled bond dynamics alters relaxation in polymers with multiple intrinsic dissociation rates-Reference-Cited by-同舟云学术

Coupled bond dynamics alters relaxation in polymers with multiple intrinsic dissociation rates

Published:2023 Issue:15 Volume:19 Page:2716-2725
ISSN:1744-683X
Container-title:Soft Matter
language:en
Short-container-title:Soft Matter

Author:

Wagner Robert J.¹^ORCID,Vernerey Franck J.²^ORCID

Affiliation:

1. Sibley School of Mechanical & Aerospace Engineering, Cornell University, Ithaca, NY, USA

2. Department of Mechanical Engineering, Program of Materials Science & Engineering, University of Colorado, Boulder, CO, USA

Abstract

Network models of multi-bond-type dynamic polymers predict that stable bond relaxation is coupled with the kinetics of nearby dynamic bonds. Thus, we append a rule of mixture to TNT to unveil the micromechanical origins of complex polymer relaxation.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SM/D3SM00014A

Reference66 articles.

1. Double-Network Hydrogels with Extremely High Mechanical Strength

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4. Fracture of dual crosslink gels with permanent and transient crosslinks

5. Mechanochemistry unveils stress transfer during sacrificial bond fracture of tough multiple network elastomers

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