Ring-fused hexahydro-1,2,4,5-tetrazines: synthesis, structure, and mechanistic studies on isolable rotational isomers
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Published:2023
Issue:6
Volume:59
Page:700-703
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ISSN:1359-7345
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Container-title:Chemical Communications
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language:en
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Short-container-title:Chem. Commun.
Author:
Toda Yasunori1ORCID,
Kooguchi Airi1,
Sukegawa Kimiya1,
Kikuchi Ayaka1,
Suga Hiroyuki1ORCID
Affiliation:
1. Department of Materials Chemistry, Faculty of Engineering, Shinshu University, 4-17-1, Wakasato, Nagano, 380-8553, Japan
Abstract
Here, we report the design and synthesis of isolable rotational isomers with a hexahydro-1,2,4,5-tetrazine core. The mechanism of the isomerization via a twist-boat conformation was elucidated by DFT calculations.
Funder
Japan Society for the Promotion of Science
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis
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