Synthesis, characterization, and reactivity of a chiral Fe(iv)–oxo complex bearing an l-proline-derived aminopyridine ligand-Reference-Cited by-同舟云学术

Synthesis, characterization, and reactivity of a chiral Fe(iv)–oxo complex bearing an l-proline-derived aminopyridine ligand

Published:2018 Issue:11 Volume:42 Page:8315-8319
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Du Junyi¹²³⁴⁵,Zhang Jisheng¹²³,Zhu Jianhua¹²³,Xia Chungu¹²³,Sun Wei¹²³^ORCID

Affiliation:

1. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Center for Excellence in Molecular Synthesis, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences

2. Lanzhou

3. P. R. China

4. University of Chinese Academy of Sciences

5. Beijing 100049

Abstract

A chiral nonheme Fe(iv)–oxo complex was synthesized and spectroscopically characterized. Its reactivity in C–H activation as well as in asymmetric sulfoxidation and C–H hydroxylation was investigated.

Funder

Natural Science Foundation of Jiangsu Province

National Natural Science Foundation of China

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C8NJ00964C

Reference75 articles.

1. Dioxygen Activation by Enzymes with Mononuclear Non-Heme Iron Active Sites