Metal–organic frameworks constructed from an [MS4Cux]x−2 (M = W, Mo) unit: isomerization of the cluster unit induced by temperature-Reference-Cited by-同舟云学术

Metal–organic frameworks constructed from an [MS4Cux]x−2 (M = W, Mo) unit: isomerization of the cluster unit induced by temperature

Published:2021 Issue:38 Volume:23 Page:6650-6654
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Meng Mei-Mei¹,Xi Ji-Ming¹,Wang Li-Fei¹,Zhu Rui¹,Zhang Rui¹,Lu Zhen-Zhong¹²^ORCID,Zheng He-Gen²^ORCID,Huang Wei¹³

Affiliation:

1. Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM), Nanjing Tech University (NanjingTech), 30 South Puzhu Road, Nanjing 211800, China

2. State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, P. R. China

3. Institute of Flexible Electronics (IFE), Northwestern Polytechnical University (NPU), 127 West Youyi Road, Xi'an 710072, China

Abstract

Two MOFs based on [WS4Cu4]2+ or unprecedented [WS4Cu6]4+·I−·[WS4Cu6]4+, and a MOF based on [MoS4Cu4]2+ with 9,10-di(pyridin-4-yl)anthracene were obtained. Temperature was important for the isomerization of [WS4Cux]x−2 in the formation of two MOFs based on [WS4Cux]x−2.

Funder

China Postdoctoral Science Foundation

National Natural Science Foundation of China

Government of Jiangsu Province

Nanjing University

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CE/D1CE00647A

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