Platinum metal complexes of potentially chelating alkene–sulphur and alkene–selenium ligands. The synthesis by chalcogen dealkylation and X-ray structures of the dimeric complexes [{PtI(SCH2CH2CMeCH2)}2] and [{PtI(PPh3)(SCH2CH2CMeCH2)}2], and a dynamic nuclear magnetic resonance study of [{PtI(L)(SCH2CH2CMeCH2)}2][L = PPh3, PPh2Me, or As(CH2SiMe3)3]
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/1990/DT/DT9900001697
Reference27 articles.
1. Platinum metal complexes of potentially chelating alkene–thioether and alkene–selenoether ligands: synthesis and dynamic nuclear magnetic resonance study of [MX2{MeE(CH2)nCHCH2}](M = Pt or Pd; X = Cl, Br, or I; E = S or Se; n= 2 or 3) and the X-ray structure of cis-dibromo(2-thia-6-heptene)platinum(II), [PtBr2{{MeS(CH2)3CHCH2}]
2. Platinum metal complexes of potentially chelating alkene thioether and selenoether ligands: the synthesis and dynamic nuclear magnetic resonance study of [MX2{E[(CH2)nCRCR2]2}](M = Pt or Pd; X = Cl, Br, or I; E = S or Se; n= 2 or 3; R = H or Me) and the X-ray crystal structure of cis-di-iodo-(5-thianona-1,8-diene)platinum(II), [PtI2{S[(CH2)2CHCH2]2}]
3. Beiträge zur Kenntniss der Platinäthyl‐sulfidverbindungen
4. Polynuclear complexes of palladium(II) with halogen and sulfur bridges
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