Synthesis and characterization of octamolybdates containing co-ordinatively bound salicylideneiminato and methioninato (MetO) ligands. Crystal structures of [NH3Pr]2[Mo8O22(OH)4(OC6H4CHNPr-2)2]·6MeOH and [Hmorph]4[Mo8O24(OH)2(MetO)2]·4H2O (morph = morpholine)
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/1990/DT/DT9900001125
Reference25 articles.
1. Oxy-methoxy compounds of molybdenum(VI) and their relationship to the selective oxidation of methanol over molybdate catalysts
2. Derivatized polyoxomolybdates. Synthesis and characterization of oxomolybdate clusters containing coordinatively bound diazenido units. Crystal and molecular structure of the octanuclear oxomolybdate (NHEt3)2(n-Bu4N)2[Mo8O20(NNPh)6] and comparison to the structures of the parent oxomolybdate .alpha.-(n-Bu4N)4[Mo8O26] and the tetranuclear (diazenido)oxomolybdates (n-Bu4N)2[Mo4O10(OMe)2(NNPh)2] and (n-Bu4N)2[Mo4O8(OMe)2(NNC6H4NO2)4]
3. Coordination complexes of polyoxomolybdate anions. Characterization of a tetranuclear core from reactions in methanol: syntheses and structures of two polyoxomolybdate alcoholates, (MePPh3)2[Mo4O10(OCH3)6] and (n-Bu4N)2[Mo4O10(OCH3)2(OC6H4O)2], and their relationship to a general class of tetranuclear cluster types [Mo4Ox(OMe)2(L)y(LL)z]2-
4. Polyoxomolybdate-o-benzoquinone interactions. Synthesis and structure of a diacetal derivative, [Mo4O15(OH)(C14H8)]3-, from 9,10-phenanthrenequinone carbonyl insertion. Comparison to the reaction products with tetrachloro-1,2-benzoquinone, the ligand-bridged binuclear complexes [(MoO2Cl2)2L]2-, L = (C6Cl2O4)2- and (C2O4)2-, formed via carbonyl insertion and chloride transfer
5. Structure of oxonium tris(triethylammonium) octamolybdate(4–) dihydrate, (C6H16N)3(H3O)[Mo8O26].2H2O
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