Mechanistic understanding of the thermal-assisted photocatalytic oxidation of methanol-to-formaldehyde with water vapor over Pt/SrTiO<sub>3</sub>-Reference-Cited by-同舟云学术

Mechanistic understanding of the thermal-assisted photocatalytic oxidation of methanol-to-formaldehyde with water vapor over Pt/SrTiO₃

Published:2024 Issue:20 Volume:26 Page:14960-14969
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Deitermann Michel¹²,Sato Takuma²^ORCID,Haver Yannik¹^ORCID,Schnegg Alexander²^ORCID,Muhler Martin¹²^ORCID,Mei Bastian Timo¹³^ORCID

Affiliation:

1. Laboratory of Industrial Chemistry, Ruhr University Bochum, 44780 Bochum, Germany

2. Max Planck Institute for Chemical Energy Conversion, 45470 Mülheim an der Ruhr, Germany

3. Photocatalytic Synthesis Group, Faculty of Science & Technology of the University of Twente, PO Box 217, Enschede, The Netherlands

Abstract

Thermal-assisted photocatalytic methanol conversion with water vapour over Pt/SrTiO3 facilitates formaldehyde formation from surface-absorbed methoxy; formyl is the key intermediate in concurrent reactions, and formate poisons the catalyst.

Funder

Deutsche Forschungsgemeinschaft

Bundesministerium für Bildung und Forschung

Max-Planck-Gesellschaft

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D4CP01106F

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