Stretching [8]cycloparaphenylene with encapsulated potassium cations: structural and theoretical insights into core perturbation upon four-fold reduction and complexation

Author:

Rogachev Andrey Yu.1234ORCID,Zhou Zheng15674ORCID,Liu Shuyang1234,Wei Zheng15674ORCID,Schaub Tobias A.8910114ORCID,Jasti Ramesh8910114ORCID,Petrukhina Marina A.15674ORCID

Affiliation:

1. Department of Chemistry

2. Illinois Institute of Technology

3. Chicago

4. USA

5. University at Albany

6. State University of New York

7. Albany

8. Department of Chemistry & Biochemistry

9. Materials Science Institute and Knight Campus for Accelerating Scientific Impact

10. University of Oregon

11. Eugene

Abstract

Structural and theoretical analysis of a highly-charged [8]cycloparaphenylene reveals drastic elliptic distortion and unique metal encapsulation of the macrocyclic host upon reduction.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference72 articles.

1. M. A. Petrukhina and L. T.Scott , Fragments of Fullerenes and Carbon Nanotubes: Designed Synthesis, Unusual Reactions, and Coordination Chemistry , Wiley , Hoboken, New Jersey , 2012

2. Contorted Polycyclic Aromatics

3. Chirality in curved polyaromatic systems

4. Toward Negatively Curved Carbons

5. Alkyne Origami: Folding Oligoalkynes into Polyaromatics

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