Reversible borohydride formation from aluminium hydrides and {H(9-BBN)}2: structural, thermodynamic and reactivity studies-Reference-Cited by-同舟云学术

Reversible borohydride formation from aluminium hydrides and {H(9-BBN)}2: structural, thermodynamic and reactivity studies

Published:2019 Issue:29 Volume:48 Page:10845-10852
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Caise Alexa¹²³⁴⁵,Kolychev Eugene L.¹²³⁴⁵,Hicks Jamie¹²³⁴⁵,Fuentes M. Ángeles¹²³⁴⁵,Goicoechea Jose M.¹²³⁴⁵^ORCID,Aldridge Simon¹²³⁴⁵^ORCID

Affiliation:

1. Inorganic Chemistry Laboratory

2. Department of Chemistry

3. University of Oxford

4. Oxford

5. UK

Abstract

Aluminium borohydrides of the type (Nacnac)Al(R){H₂(9-BBN)} are characterized by borane dissociation in solution under ambient conditions. This behaviour is critical to the ability of such complexes to reduce CO₂.

Funder

Engineering and Physical Sciences Research Council

SCG Chemicals

FP7 People: Marie-Curie Actions

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT00535H

Reference61 articles.

1. Main-group elements as transition metals

2. Reactions of heavier main-group compounds with hydrogen, ammonia, ethylene and related small molecules

3. Group 14 Hydrides with Low Valent Elements for Activation of Small Molecules

4. Interaction of Multiple Bonded and Unsaturated Heavier Main Group Compounds with Hydrogen, Ammonia, Olefins, and Related Molecules

5. N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands

Cited by 6 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Quest for Active Species in Al/B-Catalyzed CO₂ Hydrosilylation;Inorganic Chemistry;2023-10-31

2. Hydroboration of a Diolate Complex Obtained by Carbon Dioxide Capture with Acenaphthenediimine Aluminum Hydride;Organometallics;2022-12-21

3. Aluminium complexes: next-generation catalysts for selective hydroboration;Dalton Transactions;2022

4. Molecular Main Group Metal Hydrides;Chemical Reviews;2021-08-27

5. Reactivity of 1,3-dichloro-1,3-bis(dimethylamino)-propenium salts with primary amines;New Journal of Chemistry;2021