Synthesis of poly(allyl 2-ylidene-acetate) and subsequent post-polymerization modification via thiol

Synthesis of poly(allyl 2-ylidene-acetate) and subsequent post-polymerization modification via thiol–ene reaction

Published:2016 Issue:27 Volume:7 Page:4525-4530
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Krappitz Tim¹²³⁴⁵,Brauer Daniel¹²³⁴⁵,Theato Patrick¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Institute for Technical and Macromolecular Chemistry

3. University of Hamburg

4. D-20146 Hamburg

5. Germany

Abstract

Poly(allyl 2-ylidene-acetate) (M_w = 125 300 g mol⁻¹) was synthesized via rhodium mediated catalysis of allyl 2-diazoacetate and its polymerization kinetics and polymer characteristics are presented and discussed. Furthermore, post-polymerization modification utilized the reactive character of poly(allyl 2-ylidene-acetate) by means of thiol–ene reactions.

Funder

Fulbright Commission

Studienstiftung des Deutschen Volkes

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2016/PY/C6PY00818F

Reference27 articles.

1. P. Theato and H.Klok, Functional Polymers by Post-Polymerization Modification: Concepts, Guidelines, and Applications, 2013

2. C1 polymerisation and related C–C bond forming ‘carbeneinsertion’ reactions