Two electrolyte decomposition pathways at nickel-rich cathode surfaces in lithium-ion batteries-Reference-Cited by-同舟云学术

Two electrolyte decomposition pathways at nickel-rich cathode surfaces in lithium-ion batteries

Published:2022 Issue:8 Volume:15 Page:3416-3438
ISSN:1754-5692
Container-title:Energy & Environmental Science
language:en
Short-container-title:Energy Environ. Sci.

Author:

Rinkel Bernardine L. D.¹^ORCID,Vivek J. Padmanabhan²³^ORCID,Garcia-Araez Nuria²³^ORCID,Grey Clare P.¹³^ORCID

Affiliation:

1. Department of Chemistry, University of Cambridge, Cambridge CB2 1EW, UK

2. School of Chemistry, University of Southampton, Southampton SO17 1BJ, UK

3. The Faraday Institution, Harwell Campus, Didcot OX11 0RA, UK

Abstract

NMR and operando gas measurements show that at low potentials, EC is dehydrogenated to VC, whereas at high potentials, EC is chemically oxidised to CO2, CO and H2O, where the water that is formed induces secondary decomposition reactions.

Funder

Engineering and Physical Sciences Research Council

Faraday Institution

European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/EE/D1EE04053G

Reference111 articles.

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5. Capacity Fading of Ni-Rich Li[NixCoyMn1–x–y]O2 (0.6 ≤ x ≤ 0.95) Cathodes for High-Energy-Density Lithium-Ion Batteries: Bulk or Surface Degradation?

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