Transition-metal-free and base promoted C–C bond formation via C–N bond cleavage of organoammonium salts

Author:

Zhang Tao1,Wang Kunyu1,Ke Yuting1,Tang Yuanyuan1,Liu Long1ORCID,Huang Tianzeng1,Li Chunya1,Tang Zhi1,Chen Tieqiao1ORCID

Affiliation:

1. Key Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources, Hainan Provincial Key Lab of Fine Chem, Hainan Provincial Fine Chemical Engineering Research Center, Hainan University, Haikou, 570228, China

Abstract

Only mediated by KOtBu, a deaminative carbon–carbon bond forming reaction of organoammonium salts with benzyl C(sp3)–H bond was developed.

Funder

Natural Science Foundation of Hainan Province

Hainan University

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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