Hydroxyl carboxylate anion catalyzed depolymerization of biopolyesters and transformation to chemicals

Author:

Zhao Yanfei12,Zhang Hui12,Wu Fengtian13,Li Rongxiang12,Tang Minhao12,Wang Yusi12,Zeng Wei12,Han Buxing12ORCID,Liu Zhimin12ORCID

Affiliation:

1. Beijing National Laboratory for Molecular Sciences, CAS Laboratory of Colloid and Interface and Thermodynamics Department, CAS Research/Education Center for Excellence in Molecular Sciences, Center for Carbon Neutral Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China

2. University of Chinese Academy of Sciences, Beijing 100049, China

3. Jiangxi Province Key Laboratory of Polymer Micro/Nano Manufacturing and Devices, Jiangxi Province Key Laboratory of Synthetic Chemistry, East China University of Technology, Economic Development Zone, Guanglan Avenue 418, Nanchang 330013, China

Abstract

Hydroxyl carboxylate-based ionic liquids can achieve degradation of biopolyesters derived from hydroxyl carboxylic acids into various chemicals under mild and metal-free conditions.

Funder

National Natural Science Foundation of China

National Key Research and Development Program of China

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

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