Synthesis of heat storage ceramic λ-Ti3O5 using titanium chloride as the starting material

Author:

Kubota Tomoko1,Seiki Riku1,Fujisawa Akito1,Fadilla Akhmad Fadel1,Jia Fangda2,Ohkoshi Shin-ichi2ORCID,Tokoro Hiroko1ORCID

Affiliation:

1. Department of Materials Science, Institute of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8573, Japan

2. Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan

Abstract

Simple synthesis method for λ-Ti3O5 was reported. The λ-Ti3O5 transitions to β-Ti3O5 with 7.78 kJ mol−1 of heat energy by 300 MPa pressure applying. The relationship between crystalline volume and threshold pressure were studied.

Funder

Yazaki Memorial Foundation for Science and Technology

Japan Society for the Promotion of Science

Fusion Oriented REsearch for disruptive Science and Technology

Japan Science and Technology Agency

Publisher

Royal Society of Chemistry (RSC)

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