New enzymatic methods for the synthesis of primary α-aminonitriles and unnatural α-amino acids by oxidative cyanation of primary amines with d-amino acid oxidase from porcine kidney-Reference-Cited by-同舟云学术

New enzymatic methods for the synthesis of primary α-aminonitriles and unnatural α-amino acids by oxidative cyanation of primary amines with d-amino acid oxidase from porcine kidney

Published:2017 Issue:2 Volume:19 Page:418-424
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Kawahara Nobuhiro¹²³⁴⁵,Yasukawa Kazuyuki¹²³⁴⁵,Asano Yasuhisa¹²³⁴⁵

Affiliation:

1. Biotechnology Research Center and Department of Biotechnology

2. Toyama Prefectural University

3. Imizu

4. Japan

5. Asano Active Enzyme Molecule Project

Abstract

Oxidation of amino groups in amines or amino acids activates the sp³ C_α–H bond to form imines, making the alpha carbon atom a preferable target for nucleophilic reagents such as cyanide.

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/GC/C6GC02003H

Reference26 articles.

1. Ueber die künstliche Bildung der Milchsäure und einen neuen, dem Glycocoll homologen Körper;

2. Some recent applications of α-amino nitrile chemistry

3. Continuous-Flow Oxidative Cyanation of Primary and Secondary Amines Using Singlet Oxygen

4. Enantioselective synthesis of (S)-amino acids by phenylalanine dehydrogenase from Bacillus sphaericus: use of natural and recombinant enzymes

5. Structure and Function of Amino Acid Ammonia-lyases

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