Dispersion-controlled docking preference: multi-spectroscopic study on complexes of dibenzofuran with alcohols and water-Reference-Cited by-同舟云学术

Dispersion-controlled docking preference: multi-spectroscopic study on complexes of dibenzofuran with alcohols and water

Published:2019 Issue:29 Volume:21 Page:16032-16046
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Bernhard D.¹²³⁴^ORCID,Fatima M.⁵⁶⁷⁸⁹^ORCID,Poblotzki A.¹⁰¹¹¹²⁴^ORCID,Steber A. L.⁵⁶⁷⁸⁹^ORCID,Pérez C.⁵⁶⁷⁸⁹^ORCID,Suhm M. A.¹⁰¹¹¹²⁴^ORCID,Schnell M.⁵⁶⁷⁸⁹^ORCID,Gerhards M.¹²³⁴^ORCID

Affiliation:

1. TU Kaiserslautern

2. Fachbereich Chemie & Research Center Optimas

3. D-67663 Kaiserslautern

4. Germany

5. Deutsches Elektronen-Synchrotron (DESY)

6. Notkestr. 85

7. D-22607 Hamburg

8. Germany & Institute of Physical Chemistry

9. Christian-Albrechts-Universität zu Kiel

10. Institut für Physikalische Chemie

11. Universität Göttingen

12. D-37077 Göttingen

Abstract

The planarity and rigidity of dibenzofuran inverts the docking preference for increasingly bulky R-OH solvent molecules, compared to the closely related diphenyl ether. Now, London dispersion favors OH⋯π hydrogen bonding.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CP/C9CP02635E

Reference81 articles.

1. Supramolecular Chemistry—Scope and Perspectives Molecules, Supermolecules, and Molecular Devices(Nobel Lecture)

2. Noncovalent Interactions: A Challenge for Experiment and Theory

3. Interactions with Aromatic Rings in Chemical and Biological Recognition