Group 6 metal complexes with a hemilabile tridentate xantsil ligand and facile insertion of tBuCN into a W–Si bond [xantsil = (9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)]

Author:

Begum Rockshana,Komuro Takashi,Tobita Hiromi

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference17 articles.

1. Transition Metal-Catalyzed Synthesis of Silicon Polymers

2. I. Ojima , Z.Li and J.Zhuin, in The Chemistry of Organic Silicon Compounds, ed. Z. Rappoport and Y. Apeloig, Wiley, New York, 1998, vol. 2, pp. 1687–1792

3. I. Ojima , in The Chemistry of Organic Silicon Compounds, ed. S. Patai and Z. Rappoport, Wiley, New York, 1989, vol. 1, pp. 1479–1526

4. Reactions of Hydrosilanes with Transition-Metal Complexes:  Formation of Stable Transition-Metal Silyl Compounds

5. Ru(xantsil)(CO)(PCy3):  Facile Generation of a Coordinatively Unsaturated Ruthenium(II) Complex Bearing 14 Valence Electrons [xantsil = (9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)]

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