Atom-economical synthesis of 1,2-bis(phosphine oxide)ethanes from calcium carbide with straightforward access to deuterium- and<sup>13</sup>C-labeled bidentate phosphorus ligands and metal complexes-Reference-Cited by-同舟云学术

Atom-economical synthesis of 1,2-bis(phosphine oxide)ethanes from calcium carbide with straightforward access to deuterium- and¹³C-labeled bidentate phosphorus ligands and metal complexes

Published:2023 Issue:4 Volume:10 Page:1022-1033
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Lotsman Kristina A.¹^ORCID,Rodygin Konstantin S.¹^ORCID,Skvortsova Irina¹,Kutskaya Anastasia M.¹,Minyaev Mikhail E.²^ORCID,Ananikov Valentine P.¹²^ORCID

Affiliation:

1. Institute of Chemistry, Saint Petersburg State University, Universitetskiy pr. 26, Stary Petergof 198504, Russia

2. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky pr. 47, Moscow 119991, Russia

Abstract

Straightforward access to bidentate phosphorus ligands and bis(phosphineoxide)ethanes is described based on atom-economic addition reaction. A practical approach was developed to incorporate2H and13C labels using easily available reagents.

Funder

Russian Science Foundation

Saint Petersburg State University

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QO/D2QO01652D

Reference125 articles.

1. Recent Developments for the Deuterium and Tritium Labeling of Organic Molecules

2. Catalytic Hydrogen Isotope Exchange Reactions in Late-Stage Functionalization