Remote C–H insertion of vinyl cations leading to cyclopentenones-Reference-Cited by-同舟云学术

Remote C–H insertion of vinyl cations leading to cyclopentenones

Published:2017 Issue:10 Volume:8 Page:6810-6814
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Cleary Sarah E.¹²³⁴,Hensinger Magenta J.¹²³⁴,Brewer Matthias¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Vermont

3. Burlington

4. USA

Abstract

Vinyl cations, generated by reacting β-hydroxy-α-diazo ketones with Lewis acids, undergo a 1,2-shift and C–H insertion to give cyclopentenone products.

Funder

National Institute of General Medical Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C7SC02768K

Reference33 articles.

1. Catalytic Carbene Insertion into C−H Bonds

2. Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion

3. Catalytic Enantioselective C−H Activation by Means of Metal−Carbenoid-Induced C−H Insertion

4. Transition Metal-Catalyzed C–H Amination: Scope, Mechanism, and Applications

5. Recent advances in transition metal-catalyzed sp3C–H amination adjacent to double bonds and carbonyl groups

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