Photocatalytic generation of a non-heme Fe(<scp>iii</scp>)-hydroperoxo species with O<sub>2</sub> in water for the oxygen atom transfer reaction-Reference-Cited by-同舟云学术

Photocatalytic generation of a non-heme Fe(iii)-hydroperoxo species with O₂ in water for the oxygen atom transfer reaction

Published:2022 Issue:42 Volume:13 Page:12332-12339
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Pugliese Eva¹^ORCID,Vo Nhat Tam¹,Boussac Alain²^ORCID,Banse Frédéric¹^ORCID,Mekmouche Yasmina³^ORCID,Simaan Jalila³^ORCID,Tron Thierry³^ORCID,Gotico Philipp²^ORCID,Sircoglou Marie¹^ORCID,Halime Zakaria¹^ORCID,Leibl Winfried²^ORCID,Aukauloo Ally¹²^ORCID

Affiliation:

1. Institut de Chimie Moléculaire et des Matériaux d'Orsay, UMR 8182, Université Paris-Saclay, CNRS, F-91405 Orsay Cedex, France

2. Université Paris-Saclay, CEA, CNRS, Institute for Integrative Biology of the Cell (I2BC), F-91191 Gif-sur-Yvette, France

3. Aix Marseille Université, Centrale Marseille, CNRS, ISM2 UMR 7313, 13397, Marseille, France

Abstract

A photoinduced iron(III)-hydroperoxo intermediate (FeIII-OOH) was trapped by bypassing the charge accumulation process, that triggers the oxygen atom transfer reaction to an alkene with O2 as sole oxygen source in water.

Funder

Institut Universitaire de France

Centre National de la Recherche Scientifique

Université Paris-Saclay

Agence Nationale de la Recherche

French Infrastructure for integrated Structural Biology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC03129A