Experimental evidence of an electronic transition in CeP under pressure using Ce L3 XAS

Author:

Joseph B.123ORCID,Torchio R.456,Benndorf C.789,Irifune T.10111213,Shinmei T.10111213,Pöttgen R.789,Zerr A.14156ORCID

Affiliation:

1. Elettra-Sincrotrone Trieste

2. Basovizza

3. Italy

4. European Synchrotron Radiation Facility

5. 38043 Grenoble Cedex

6. France

7. Institut für Anorganische und Analytische Chemie Universitat Münster

8. Münster

9. Germany

10. Geodynamics Research Center

11. Ehime University

12. Matsuyama

13. Japan

14. Laboratoire des Sciences des Procédés et des Materiaux LSPM-CNRS

15. Sorbonne Paris Cité 93430

Abstract

A direct compelling evidence of an electronic transition associated with the isostructural unit-cell volume discontinuity in CeP under pressure is provided using Ce L3-XAS. A DAC with a combination of a mini and a partially perforated anvils made of nanodiamonds permitted us to track the pressure induced changes in the 4f state of Ce in CeP.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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