Donor–acceptor cyclopropanes as ortho-quinone methide equivalents in formal (4 + 2)-cycloaddition to alkenes
Author:
Affiliation:
1. Department of Chemistry
2. Lomonosov Moscow State University
3. Moscow 119991
4. Russia
5. Kurnakov Institute of General and Inorganic Chemistry
6. Russian Academy of Sciences
Abstract
A new reactivity of donor–acceptor cyclopropanes as synthetic equivalents of o-quinone methides was revealed for 2-hydroxyarylcyclopropane diesters in their formal (4 + 2)-cycloaddition to alkenes yielding chromanes.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/OB/C8OB00377G
Reference82 articles.
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2. Cycloadditions of Donor-Acceptor Cyclopropanes and Nitriles
3. Domino-Ring Opening-Cyclization (DROC) of Donor-Acceptor (DA) Cyclopropanes
4. Synthetic Applications of Aroyl- and Nitro-substituted 2-Aryl-Cyclopropane-1,1-Dicarboxylates
5. Asymmetric Ring-Opening Reactions of Donor-Acceptor Cyclopropanes and Cyclobutanes
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