Lone pair⋯π interaction versus σ-hole appearance in metal-bonded halogens-Reference-Cited by-同舟云学术

Lone pair⋯π interaction versus σ-hole appearance in metal-bonded halogens

Published:2019 Issue:18 Volume:21 Page:2929-2939
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Khavasi Hamid Reza¹²³⁴^ORCID,Rahimi Narjes¹²³⁴

Affiliation:

1. Department of Inorganic Chemistry and Catalysis

2. Shahid Beheshti University

3. Tehran 1983963113

4. Iran

Abstract

Three complexes of N-(2,5-diluorophenyl)-2-pyrazine carboxamide and ZnX₂ have been synthesized. The crystal structures reveal that in all three coordination compounds, metal-bound halides have interacted with π systems through a negative electrostatic region.

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CE/C8CE01795F

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