Reversible C–C bond formation in group 4 metal complexes: nitrile extrusion <i>via</i> β-aryl elimination-Reference-Cited by-同舟云学术

登录注册会员服务联系我们

Reversible C–C bond formation in group 4 metal complexes: nitrile extrusion via β-aryl elimination

Published:2024 Issue: Volume: Page:
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Kulyabin Pavel S.¹^ORCID,Goryunov Georgy P.¹^ORCID,Iashin Andrei N.¹,Mladentsev Dmitry Y.¹,Uborsky Dmitry V.¹^ORCID,Ehm Christian²^ORCID,Canich Jo Ann M.³,Hagadorn John R.³,Voskoboynikov Alexander Z.¹^ORCID

Affiliation:

1. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 1/3, Moscow 119991, Russian Federation

2. Dipartimento di Scienze Chimiche, Università di Napoli Federico II, Via Cintia, Napoli 80126, Italy

3. Baytown Technology and Engineering Complex, ExxonMobil Technology and Engineering Company, Baytown, Texas 77520, USA

Abstract

Zr and Hf pyridylamides reversibly insert nitriles into M–CAr bond and release them back with cleavage of the formed C–C bond, regeneration of the M–CAr bond and the free nitrile: a first example of β-aryl elimination in early transition metals.

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC02173H

Reference71 articles.

1. Catalytic C–C Bond Activations via Oxidative Addition to Transition Metals

2. Temporary or removable directing groups enable activation of unstrained C–C bonds

3. G.Dong , Topics in Current Chemistry: C-C Bond Activation , 2014 , vol. 346

4. Metal-Catalyzed Carbon–Carbon Bond Cleavage of Unstrained Alcohols

5. Catalytic activations of unstrained C–C bond involving organometallic intermediates

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线，采集、加工和组织学术论文而形成的新型学术文献查询和分析系统，可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容，当前同舟云学术共收录了国内外主流学术期刊6万余种，收集的期刊论文及会议论文总量共计约1.5亿篇，并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询！咨询电话：010-8811{复制后删除}0370

www.globalauthorid.com

TOP