A rapid and direct method for dating blue pen ink in documents using multiset modeling of infrared spectroscopy and mass spectrometry data

Author:

Braga Kauanny B. N.1,Maciel Lanaia Í. L.2,Vaz Boniek G.2ORCID,Pinto Licarion3ORCID,Santos Jandyson M.1ORCID

Affiliation:

1. Grupo de Pesquisa em Petróleo, Energia e Espectrometria de Massas (PEM), Departamento de Química, Universidade Federal Rural de Pernambuco – UFRPE, Rua Dom Manoel de Medeiros, s/n, Recife, Pernambuco, 52171-131, Brazil

2. Instituto de Química, Universidade Federal de Goiás, Goiânia, GO, 74690-900, Brazil

3. Departamento de Química Analítica, Instituto de Química, Universidade do Estado do Rio de Janeiro, R. São Francisco Xavier, 524, Maracanã, Rio de Janeiro, RJ, 20550-013, Brazil

Abstract

A rapid and simple method for dating pen ink was developed, employing FTIR-ATR, DESI-MS, and data fusion modeling, which resulted in a predictive model with an error margin of ±5 years for pen inks of documents dating from 1960 to 2022.

Funder

Fundação de Amparo à Ciência e Tecnologia do Estado de Pernambuco

Publisher

Royal Society of Chemistry (RSC)

Subject

General Engineering,General Chemical Engineering,Analytical Chemistry

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